Intermolecular Interaction of Aqueous Dextran with Urea
Subhraraj Panda1, Achyuta Prasad Mahapatra2
1Subhraraj Panda, Physics, Centurion University of Technology and Management, Odisha, India.
2Achyuta Prasad Mahapatra, Physics, KBRC Degree College, Cuttack, India.
Manuscript received on 25 August 2019. | Revised Manuscript received on 04 September 2019. | Manuscript published on 30 September 2019. | PP: 742-748 | Volume-8 Issue-11, September 2019. | Retrieval Number: K14450981119/2019©BEIESP | DOI: 10.35940/ijitee.K1445.0981119
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© The Authors. Blue Eyes Intelligence Engineering and Sciences Publication (BEIESP). This is an open access article under the CC-BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
Abstract: In this paper, the authors have given information regarding intermolecular interactions of aqueous dextran solution in urea. The behavior of dextran in urea has been examined by the help of ultrasonic interferometer working at frequency 5MHz at different temperatures ranging from 303 K to 323 K in 5K interval. Ultrasonic speed, density, viscosity measurements have been used for the evaluation of thermodynamic parameters like Gibb’s free energy (ΔG) as well as acoustical parameters are acoustic impedance (Z), isentropic compressibility (β), intermolecular free length (Lf ) and relaxation time (τ), etc. The results have been used to throw light on the nature of the interaction among solute and solvent, interpreted in the light of structural rearrangement occurs in the aqueous dextran and urea solution.
Keywords: Dextran, acoustic impedance, isentropic compressibility, and Gibb’s free energy.
Scope of the Article: